Crystal structure of [Pd(NH3)4]3[Ir(NO2)6]2·H2O

被引:0
作者
A. A. Rybinskaya
E. A. Shusharina
P. E. Plyusnin
Yu. V. Shubin
S. V. Korenev
S. A. Gromilov
机构
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源
Journal of Structural Chemistry | 2011年 / 52卷
关键词
palladium; iridium; double complex salt; single crystal X-ray diffraction; powder X-ray diffraction; thermal analysis;
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摘要
A single crystal of [Pd(NH3)4]3[Ir(NO2)6]2·H2O double complex salt is studied by X-ray diffraction. Crystallographic characteristics are as follows: a = 21.0335(5) Å, b = 8.0592(2) Å, c = 21.3452(5) Å, β = 91.254(1)°, V = 3617.43(15) Å3, P21/c space group, Z = 4, dx = 2.714 g/cm3. Single-layer pseudohexagonal packing of complex anions is determined along the [−1 0 1] direction in the structure. Complex cations and crystallization water molecules are located between the mentioned layers.
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页码:816 / 819
页数:3
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