Heat characteristics of chemical warfare agents

被引：0
作者：
Wendy Carrick
Linda Fernee
D. Francis
机构：
[1] Defence Science and Technology Laboratory Porton Down,Environmental Sciences
来源：
Journal of Thermal Analysis and Calorimetry | 2005年 / 79卷
关键词：
TG-DTA; chemical warfare agents; dimilitarisation; heat characteristics;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The heat characteristics of sulfur mustard (H), Lewisite (L), LI, LII, LIII, yellow agent (1:1 mass/mass H and L) and H heels were investigated by thermogravimetric - differential thermal analysis (TG-DTA). The object of this study was to provide details of the effectiveness of elevated temperature on the decomposition of these agents in both an active atmosphere (air) and an inert atmosphere (nitrogen). TG-DTA measured object mass change and heat radiation/absorption corresponding to regulated temperature changes of the test materials. All agents, with the exception of one of the H heels, exhibited an endotherm suggesting evaporation of the agents rather than oxidation.
引用
收藏
页码：101 / 106
页数：5
相关论文
共 50 条
[41]   Research Progress of Nano Metal Oxides in Decontamination of Chemical Warfare Agents [J].
Guo Y. ;
Lei M. ;
Chen W. ;
Xin Y. ;
Xu W. ;
Min Q. ;
Chen L. ;
Wu Y. ;
Kong L. ;
Zuo Y. .
Cailiao Daobao/Materials Reports, 2022, 36 (11)
[42]   Nanomaterials-Enabled Sensors for Detecting and Monitoring Chemical Warfare Agents [J].
Kilani, Mohamed ;
Mao, Guangzhao .
SMALL, 2025, 21 (09)
[43]   Applications of Mass Spectrometry in Investigations of Alleged Use of Chemical Warfare Agents [J].
Read, Robert W. .
DETECTION OF BIOLOGICAL AGENTS FOR THE PREVENTION OF BIOTERRORISM, 2010, :201-219
[44]   Surface acoustic wave sensing detection system for chemical warfare agents [J].
Chen Chuanzhi ;
Ma Jinyi ;
Zuo Boli ;
Jiang Hongmin ;
Zhang Hongxing .
Proceedings of the First International Symposium on Test Automation & Instrumentation, Vols 1 - 3, 2006, :1946-1949
[45]   USE OF SOLID-PHASE EXTRACTION IN DETERMINATION OF CHEMICAL WARFARE AGENTS [J].
TORNES, JA ;
OPSTAD, AM ;
JOHNSEN, BA .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1991, 44 (04) :209-225
[46]   Derivatisation reactions in the chromatographic analysis of chemical warfare agents and their degradation products [J].
Black, RM ;
Muir, B .
JOURNAL OF CHROMATOGRAPHY A, 2003, 1000 (1-2) :253-281
[47]   Poly High Internal Phase Emulsion for the Immobilization of Chemical Warfare Agents [J].
Wright, Alexander J. ;
Main, Marcus J. ;
Cooper, Nicholas J. ;
Blight, Barry A. ;
Holder, Simon J. .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (37) :31335-31339
[48]   Blaptica dubia as sentinels for exposure to chemical warfare agents - a pilot study [J].
Worek, Franz ;
Seeger, Thomas ;
Neumaier, Katharina ;
Wille, Timo ;
Thiermann, Horst .
TOXICOLOGY LETTERS, 2016, 262 :12-16
[49]   Cerium oxide for the destruction of chemical warfare agents: A comparison of synthetic routes [J].
Janos, Pavel ;
Henych, Jiri ;
Pelant, Ondrej ;
Pilarova, Vera ;
Vrtoch, Lubos ;
Kormunda, Martin ;
Mazanec, Karel ;
Stengl, Vaclav .
JOURNAL OF HAZARDOUS MATERIALS, 2016, 304 :259-268
[50]   DETECTION OF CHEMICAL WARFARE NERVE AGENTS VIA A BECKMANN FRAGMENTATION OF ALDOXIME [J].
Lee, Jin Young ;
Lee, Yong Han ;
Byun, Yong Gwan .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2012, 187 (05) :641-649
12345