Heat characteristics of chemical warfare agents

被引:0
作者
Wendy Carrick
Linda Fernee
D. Francis
机构
[1] Defence Science and Technology Laboratory Porton Down,Environmental Sciences
来源
Journal of Thermal Analysis and Calorimetry | 2005年 / 79卷
关键词
TG-DTA; chemical warfare agents; dimilitarisation; heat characteristics;
D O I
暂无
中图分类号
学科分类号
摘要
The heat characteristics of sulfur mustard (H), Lewisite (L), LI, LII, LIII, yellow agent (1:1 mass/mass H and L) and H heels were investigated by thermogravimetric - differential thermal analysis (TG-DTA). The object of this study was to provide details of the effectiveness of elevated temperature on the decomposition of these agents in both an active atmosphere (air) and an inert atmosphere (nitrogen). TG-DTA measured object mass change and heat radiation/absorption corresponding to regulated temperature changes of the test materials. All agents, with the exception of one of the H heels, exhibited an endotherm suggesting evaporation of the agents rather than oxidation.
引用
收藏
页码:101 / 106
页数:5
相关论文
共 50 条
  • [1] Heat characteristics of chemical warfare agents
    Carrick, W
    Fernee, L
    Francis, D
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 79 (01) : 101 - 106
  • [2] CHEMICAL WARFARE AGENTS .2. NERVE AGENTS
    SIDELL, FR
    BORAK, J
    ANNALS OF EMERGENCY MEDICINE, 1992, 21 (07) : 865 - 871
  • [3] Organophosphorus Compounds as Chemical Warfare Agents: a Review
    Delfino, Reinaldo T.
    Ribeiro, Tatiana S.
    Figueroa-Villar, Jose D.
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2009, 20 (03) : 407 - 428
  • [4] Recent Advances in Decontamination of Chemical Warfare Agents
    Khan, Abdul Wadood
    Kotta, Sabna
    Ansari, Shahid Husain
    Ali, Javed
    Sharma, Rakesh Kumar
    DEFENCE SCIENCE JOURNAL, 2013, 63 (05) : 487 - 496
  • [5] Biomonitoring of exposure to chemical warfare agents: A review
    Noort, D
    Benschop, HP
    Black, RM
    TOXICOLOGY AND APPLIED PHARMACOLOGY, 2002, 184 (02) : 116 - 126
  • [6] Novichoks - The A group of organophosphorus chemical warfare agents
    Kloske, Marcin
    Witkiewicz, Zygfryd
    CHEMOSPHERE, 2019, 221 : 672 - 682
  • [7] Photoionization and electronic structure of chemical warfare agents
    Novak, Igor
    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2025, 279
  • [8] Analysis of Chemical Warfare Agents by Portable Raman Spectrometer
    Satoh, Takafumi
    Sekioka, Ryoji
    Seto, Yasuo
    Matsumiya, Hiroyuki
    Nakagawa, Hideki
    BUNSEKI KAGAKU, 2016, 65 (09) : 539 - 545
  • [9] Revised airborne exposure limits for chemical warfare agents
    Decker, JA
    Rogers, HW
    ECOLOGICAL RISKS ASSOCIATED WITH THE DESTRUCTION OF CHEMICAL WEAPONS, 2006, : 279 - +
  • [10] Nanomaterials based decontaminants against chemical warfare agents
    Prasad, G. K.
    Ramacharyulu, P. V. R. K.
    Singh, Beer
    JOURNAL OF SCIENTIFIC & INDUSTRIAL RESEARCH, 2011, 70 (02): : 91 - 104