Two octacyanomolybdate(IV)-M(II) (M = Mn, Co) bimetallic assemblies: Crystal structures and magnetic properties

被引：0
作者：
S. L. Ma
S. Ren
机构：
[1] Tianjin University of Commerce,Department of Application Chemistry, College of Science
来源：
Russian Journal of Coordination Chemistry | 2009年 / 35卷
关键词：
Coordination Chemistry; Bipy; Tetragonal System; Variable Temperature Magnetic Susceptibility; Yellow Block Crystal;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two cyano-bridged bimetallic complexes {[M2(H2O)4Mo(CN)8] · 4H2O}n [M = Mn (I) and Co (II)] have been synthesized and structurally characterized. The single-crystal X-ray analyses reveal that these two compounds have three-dimensional structures, and cell parameters are similar in a tetragonal system with space group I\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \bar 4 $$\end{document}. In the both complexes, each [Mo(CN)8]4− building block is linked with M2+ [M = Mn and Co] ions through its eight CN ligands. Each M2+ center is connected to four Mo units forming a three-dimensional framework. In addition, magnetic studies of these complexes have been presented.
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页码：766 / 771
页数：5
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