Features of the phase composition, acidity, and isomerization activity of Pt/WO3/ZrO2 catalysts

被引:0
作者
M. D. Smolikov
V. A. Shkurenok
O. V. Dzhikiya
D. I. Kir’yanov
E. V. Zatolokina
A. S. Belyi
机构
[1] Russian Academy of Sciences,Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch
来源
Russian Chemical Bulletin | 2020年 / 69卷
关键词
isomerization; -heptane; tungstated zirconia; platinum;
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学科分类号
摘要
Textural characteristics, phase composition, and acidic properties of Pt/WO3/ZrO2 catalysts for C7-alkanes isomerization were studied. It was shown that the most active and selective catalysts are samples with WO3 content of 15–25 wt.% with a fraction of the active tetragonal phase of ZrO2 of 73–94 wt.%. It was found that an increase in the number of Bronsted acid sites contributes to an increase in the activity of tungstated zirconia catalysts in the isomerization of n-heptane.
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页码:1714 / 1718
页数:4
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共 80 条
[1]  
Khurshid M(2009)undefined Appl. Catal., A, Gen. 362 75-undefined
[2]  
Al-Daous M A(2011)undefined Appl. Catal., A, Gen. 397 82-undefined
[3]  
Hattori H(2017)undefined Cat. Ind. 9 54-undefined
[4]  
Al-Khattaf S S(2011)undefined Catal. Today 164 148-undefined
[5]  
Kaucký D(2014)undefined React. Kinet. Mech. Catal. 113 69-undefined
[6]  
Wichterlová B(2011)undefined Catal. Today 166 67-undefined
[7]  
Dedecek J(2007)undefined Appl. Catal., A, Gen. 318 178-undefined
[8]  
Sobalik Z(2009)undefined Nat. Chem. 1 722-undefined
[9]  
Jakubec I(2013)undefined J. Catal. 299 119-undefined
[10]  
Smolikov M D(1998)undefined Appl. Catal., A, Gen. 168 93-undefined