Sn/Cu-TiO2 nanoparticles produced via sol-gel method: Synthesis, characterization, and photocatalytic activity

被引:0
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作者
R. Mohammadi
B. Massoumi
机构
[1] Payame Noor University,Department of Chemistry
关键词
Sn/Cu-TiO; nanoparticles; photocatalytic degradation; activation energy; electrical energy per order;
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摘要
TiO2 and Sn/Cu-TiO2 nanoparticles with different Sn/Cu contents have been synthesized and characterized by different analysis methods such as XRD, TEM, and BET. Sn/Cu-TiO2 was preferential to TiO2 with 2,5-fold increase in photodegradation rate of different types of dyes such as methyl orange, methylene blue and methyl red. This activity was relevant to the influences of co-doping on the physicochemical properties and surface interfacial charge transfer mechanisms. An optimum synergetic effect was found for a mass ratio of Sn/TiO2 equal to 0.75% and Cu/TiO2 equal to 0.5%. The degradation reaction fit well to a Langmuir-Hinshelwood kinetic model indicating the reaction rate is depended on initial adsorption step.
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页码:1184 / 1190
页数:6
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