Advances in self-assembled ultrathin polyoxomolybdates multilayers

被引:0
作者
Yang L.-B. [1 ]
Wang X.-F. [1 ]
Xie A.-J. [1 ,2 ]
Hu G. [1 ]
Shen Y.-H. [1 ,2 ]
机构
[1] School of Chemistry and Chemical Engineering, Anhui University
[2] State Key Laboratory of Coordination Chemistry, Nanjing University
来源
Frontiers of Materials Science in China | 2009年 / 3卷 / 1期
基金
高等学校博士学科点专项科研基金; 中国国家自然科学基金;
关键词
Multilayer films; Polyoxomolybdates; Self-assembled;
D O I
10.1007/s11706-009-0019-y
中图分类号
学科分类号
摘要
The research on the assembly and function of organized molecular films has gained more and more interest. Electrostatic interactions can be employed to assemble polyoxomolybdates in surface confined multilayers. Ultrathin multilayer films of polyoxomolybdates and organic molecules by the self-assembly method have been reviewed. At the same time, self-assemblies in aqueous solution are also reported, such as wheel-shaped clusters (Mo154), hollow spherical "blackberry"-like vesicles (Mo72Fe30) and Keggin structures. Polyoxomolybdate multilayers are promising candidates for diverse applications including electrocatalytic, photo- and electrochromic systems. The development in this particular field of materials science may be highlighted in the future. © 2009 Higher Education Press and Springer-Verlag GmbH.
引用
收藏
页码:1 / 8
页数:7
相关论文
共 46 条
[1]  
Shen J.C., Zhang X., Sun Y.P., Molecular deposition films, Progress in Nature Science, 6, pp. 13-21, (1996)
[2]  
Krass H., Papastavrou G., Kurth D.G., Layer-by-Layer self-assembly of a polyelectrolyte bearing metal ion coordination and electrostatic functionality, Chemistry of Materials, 15, pp. 196-203, (2003)
[3]  
Decher G., Fuzzy nanoassemblies: Toward layered polymeric multicomposites, Science, 277, pp. 1232-1237, (1997)
[4]  
Schmitt J., Decher G., Dressick W.J., Metal nanoparticle/polymer superlattice films: Fabrication and control of layer structure, Advanced Materials, 9, pp. 61-65, (1997)
[5]  
Zhang X., Shen J.C., Self-assembled ultrathin films: From layered nanoarchitectures to functional assemblies, Advanced Materials, 11, pp. 1139-1143, (1999)
[6]  
Dutta A.K., Ho T., Zhang L., Nucleation and growth of lead sulfide nano-and microcrystallites in supramolecular polymer assemblies, Chemistry of Materials, 12, pp. 1042-1048, (2000)
[7]  
Kozhenikov I.V., Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions, Chemical Reviews, 98, pp. 171-198, (1998)
[8]  
Mizuno N., Misono M., Heterogeneous catalysis, Chemical Reviews, 98, pp. 199-218, (1998)
[9]  
Weinstook I.A., Homogeneous-phase electron-transfer reactions of polyoxometalates, Chemical Reviews, 98, pp. 113-170, (1998)
[10]  
Sadakane M., Stechhan E., Electrochemical properties of polyoxometalates as electrocatalysts, Chemical Reviews, 98, pp. 219-238, (1998)