Complex dielectric permittivity and electrical conductivity of (TlGaSe2)1–х (TlInS2)х solid solutions in an AC electric field

被引:0
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作者
S. N. Mustafaeva
S. M. Asadov
M. M. Gojaev
A. B. Magerramov
机构
[1] Academy of Sciences of Azerbaijan,Institute of Physics
[2] Academy of Sciences of Azerbaijan,Nagiyev Institute of Catalysis and Inorganic Chemistry
[3] Sumqayit State University,undefined
来源
Inorganic Materials | 2016年 / 52卷
关键词
(TlGaSe; ); (TlInS; ); solid solutions; dielectric permittivity; hopping conduction; frequency dispersion; dielectric loss;
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学科分类号
摘要
We have synthesized the TlGaSe2 and TlInS2 compounds and (TlGaSe2)1–х (TlInS2)х (х = 0.2, 0.4) solid solutions. The phase composition of the (TlGaSe2)1–х (TlInS2)х (х = 0, 0.2, 0.4, 1.0) samples and crystals grown using these materials has been determined by X-ray diffraction. TlGaSe2, TlInS2, and the TlGaSe2-based solid solutions (monoclinic crystal system) have been shown to be isostructural with each other. The dielectric properties of the grown crystals have been studied in ac electric fields at frequencies in the range f = 5 × 104 to 3.5 × 107 Hz. We have identified the relaxation nature of the dielectric permittivity of the crystals, the origin of the dielectric loss, and the hopping carrier transport mechanism in the samples. It has been shown that, with increasing x, the mean hop distance and time in the (TlGaSe2)1–х (TlInS2)х solid solutions decrease, whereas the concentration of deep traps and the energy spread of the states localized in the band gap increase.
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页码:1096 / 1102
页数:6
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