Preparation of monodisperse PMMA particles by dispersion polymerization of MMA using poly(styrene-co-methacrylic acid) copolymer as a steric stabilizer

被引：0
作者：
Shinji Watanabe
Takashi Kobayashi
Hiroshi Sumitomo
Miki Murata
Yuzuru Masuda
机构：
[1] Kitami Institute of Technology,Department of Materials Science and Engineering
来源：
Polymer Bulletin | 2010年 / 65卷
关键词：
Dispersion polymerization; Methyl methacrylate; Poly(styrene-co-methacrylic acid); Monodisperse particles; Steric stabilizer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Dispersion polymerization of MMA was conducted using poly(styrene-co-methacrylic acid) copolymer as a steric stabilizer in an aqueous methanol medium. Various composition copolymers were easily prepared with a conventional radical polymerization by changing the monomer ratios of styrene to methacrylic acid, and were employed as a steric stabilizer for dispersion polymerization. The copolymers prepared with monomer ratios of 1.25–1.50 were found to be suitable steric stabilizers for dispersion polymerization. A very small amount of copolymer (0.6 wt% based on MMA) could act as a steric stabilizer effectively to obtain monodisperse PMMA particles. The particle size decreased with increasing the solvent polarity from 4 to 0.14 μm.
引用
收藏
页码：543 / 550
页数：7
相关论文
共 77 条
[1]  
Narayanan K(2001)Preparation of linear and crosslinked polymer microspheres by dispersion polymerization J Macromol Sci Polym Rev C41 79-undefined
[2]  
Jayachandran N(1996)Reactive surfactants in heterophase polymerization. 2. Maleate based poly(ethylene oxide) macromonomers as steric stabilizer precursors in the dispersion polymerization of styrene in ethanol–water media Macromolecules 29 4508-undefined
[3]  
Chatterji PR(1997)Dispersion copolymerization of poly(oxyethylene) macromonomers and styrene J Polym Sci A 35 3131-undefined
[4]  
Lacroix-Desmazes P(1996)Dispersion polymerization of styrene in polar solvents: effect of reaction parameters on microsphere surface composition and surface properties, size and size distribution, and molecular weight J Polym Sci A 34 1857-undefined
[5]  
Guyot A(2009)Influence of poly(methyl methacrylate) particles with different initial temperature rising ramps on size distribution in dispersion polymerization J Appl Polym Sci 112 917-undefined
[6]  
Capek I(2005)Negatively charged ultrafine black particles of P(MMA-co-EGDMA) by dispersion polymerization for electrophoretic displays Macromolecules 38 7485-undefined
[7]  
Riza M(1993)Control of particle size in dispersion polymerization of methyl methacrylate J Polym Sci A 31 1393-undefined
[8]  
Akashi M(2008)Dispersion polymerization of methyl methacrylate: effect of stabilizer concentration J Appl Polym Sci 107 2453-undefined
[9]  
Bamnolker H(1994)Dispersion polymerization of styrene in aqueous alcohol solution: effects of reaction parameters on the polymer particle formation Polym Int 34 339-undefined
[10]  
Margel S(1992)Hydroxypropyl cellulose (HPC)-stabilized dispersion polymerization of styrene in polar solvents: effect of reaction parameters J Polym Sci A 30 2765-undefined
12345678