Preparation and characterization of nanocomposite membranes based on PVC/TiO2 anatase for the separation of toluene/n-heptane mixtures via pervaporation

被引:0
作者
A. Tabbiche
L. Aouinti
机构
[1] Université des Sciences et de la Technologie d’Oran Mohamed-Boudiaf USTOMB,Laboratoire des Eco
[2] Université d’Oran Es-Senia,Matériaux Fonctionnels Et Nanostructurés, Faculté de Chimie
[3] Université des Sciences et de la Technologie d’Oran Mohamed-Boudiaf USTOMB,Laboratoire de Chimie des Polymères, Département de Chimie, Faculté des Sciences
来源
Polymer Bulletin | 2023年 / 80卷
关键词
Hybrid membranes; Polyvinyl chloride; Titanium dioxide anatase; Pervaporation; Toluene/n-heptane;
D O I
暂无
中图分类号
学科分类号
摘要
Hybrid membranes based on polyvinyl chloride (PVC) containing 1–5 wt% of titanium dioxide anatase (TiO2 anatase) particles were prepared via the casting solution method. These membranes were characterized by XRD, FTIR, TGA, SEM, EDX, and contact angle measurements. The pervaporation (PV) and separation characteristics of toluene/n-heptane mixtures containing 50 wt% through these membranes were investigated at 56 °C. The membranes flux increased with increasing TiO2 anatase content, and the selectivity decreased; however, a significant improvement in PV performance was observed for membranes loaded with TiO2 anatase compared to pure PVC. The PVC membrane loaded with 2 wt% TiO2 anatase showed the highest separation factor of 6.27 with a normalized flux of 0.55 kg/m2.h where in absence of TiO2 anatase the corresponding values were 9.7 and 0.05 kg/m2.h.
引用
收藏
页码:643 / 666
页数:23
相关论文
共 188 条
  • [1] Ong YK(2016)Recent membrane development for pervaporation processes Prog Polym Sci 57 1-31
  • [2] Shi GM(2008)Poly(vinyl alcohol)–zeolite T mixed matrix composite membranes for pervaporation separation of water + 1,4-dioxane mixtures Sep Purif Technol 58 377-385
  • [3] Le NL(2007)Mixed matrix membranes of sodium alginate and poly(vinyl alcohol) for pervaporation dehydration of isopropanol at different temperatures Polymer 48 5417-5430
  • [4] Tang YP(2007)Blend membranes of chitosan and poly(vinyl alcohol) in pervaporation dehydration of isopropanol and tetrahydrofuran J Appl Polym Sci 103 1918-1926
  • [5] Zuo J(2020)Cu (I/II) metal-organic frameworks incorporated nanofiltration membranes for organic solvent separation J Membranes 10 313-136
  • [6] Nunes SP(2008)Pervaporation separation of toluene/alcohol mixtures using silicalite zeolite embedded chitosan mixed matrix membranes Sep Purif Technol 62 128-168
  • [7] Chung T-S(2009)Pervaporation-aided dehydration and esterification of acetic acid with ethanol using 4A Zeolite-filled cross-linked sodium alginate-mixed matrix membranes J Appl Polym Sci 113 157-174
  • [8] Veerapur RS(2000)A review on the separation of benzene/cyclohexane mixtures by pervaporation processes J Membr Sci 169 159-17130
  • [9] Patil MB(2013)Graphene-loaded sodium alginate nanocomposite membranes with enhanced isopropanol dehydration performance via pervaporation technique RSC Adv 3 17120-429
  • [10] Gudasi KB(2014)para-Toluene sulfonic acid treated clay loaded sodium alginate membranes for enhanced pervaporative dehydration of isopropanol Appl Clay Sci 101 419-1782