Hydrothermal synthesis of coherent porous V2O3/carbon nanocomposites for high-performance lithium- and sodium-ion batteries水热法制备多孔V2O3/碳复合材料用于高性能锂离子电池和钠离子电池的研究

Carbonaceous composite materials have been extensively studied in energy storage and conversion devices and commonly are fabricated from liquid precursors. In this work, we reported an unusual formation of vanadium oxide and carbon nanocomposite from microsized VO2 microspheres through a “dissolution and recrystallization” process with the assistance of LiH2PO4. The obtained vanadium oxides nanoparticles are in uniform distribution in the carbon matrix. The V2O3/carbon composite inherits the porous feature of the Ketjen black (KB) carbon and has a surface area of 76.59 m2 g−1. As an anode material for lithium/sodium-ion batteries, the V2O3/carbon nanocomposites exhibit higher capacity, better rate capability and cycling stability than the V2O3 nanoparticle counterparts. The enhanced electrochemical performances are attributed to the porous V2O3/carbon nanocomposites, which can allow the electrolyte penetration, shorten the ion diffusion distance and improve the electronic conductivity.