Facile synthesis and photocatalytic activity of bi-phase dispersible Cu-ZnO hybrid nanoparticles

被引:0
作者
Xiao Liu
HongLing Liu
WenXing Zhang
XueMei Li
Ning Fang
XianHong Wang
JunHua Wu
机构
[1] School of Chemistry and Chemical Engineering,Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering
[2] Henan University,Department of Materials Science and Engineering
[3] Shangqiu Normal University,Pioneer Research Center for Biomedical Nanocrystals
[4] South University of Science and Technology of China,undefined
[5] Korea University,undefined
来源
Nanoscale Research Letters | 2015年 / 10卷
关键词
Nanoemulsion; Bi-phase dispersible; Cu-ZnO nanoparticles; Photocatalytic performance;
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中图分类号
学科分类号
摘要
Bi-phase dispersible Cu-ZnO hybrid nanoparticles were synthesized by one-pot non-aqueous nanoemulsion with the use of poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) (PEO-PPO-PEO) as the surfactant. The transmission electron microscopy (TEM) and X-ray diffraction (XRD) show high crystallinity of the Cu-ZnO hybrid nanoparticles and an average particle size of ~19.4 nm. The ultraviolet–visible light absorbance spectrometry (UV–vis) and photoluminescence spectrophotometry (PL) demonstrate well dispersibility and excellent optical performance of Cu-ZnO hybrid nanoparticles both in organic and aqueous solvent. The X-ray photoelectron spectroscopy (XPS) confirms Cu1+ and Cu2+ in ZnO. The observation using Sudan red (III) as probe molecule reveals that the Cu-ZnO hybrid nanoparticles possess enhanced photocatalytic activity and stability which are promising for potential applications in photocatalysis.
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