Synthesis and X-Ray Crystal Structure of New Oxathiacrown Ethers Containing Sulfoxide Group and Their Metal-Binding Properties: Highly Selective Receptors for Ag+ and Cu2+

被引：0

作者：

Muhammad Ashram

机构：

[1] Mutah University,Chemistry Department

来源：

Journal of inclusion phenomena and macrocyclic chemistry | 2005年 / 51卷

关键词：

conductivity; oxathiacrown ethers; sulfoxide group; transition metal cations; X-ray crystal structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Three new oxathiacrown ethers 1, 2 and 3 containing a sulfoxide group were synthesized in a simple way. Conductometric titration studies in pure acetonitrile were employed to invistigate their binding affinities towards Ag +, Cu 2+, Pb 2+, Cd 2+, Zn 2+, Co 2+, Ni 2+, Cr 3+and Hg 2+. They were found to be selective for Ag + and Cu 2+ over the other metals investigated. Ligand 1 has the highest selectivity towards Ag +. The structure of compound 3 was confirmed by X-ray crystallography.

引用

页码：199 / 203

页数：4

共 50 条

[1] Synthesis and X-ray crystal structure of new oxathiacrown ethers containing sulfoxide group and their metal-binding properties:: Highly selective receptors for Ag+ and Cu2+
Ashram, M
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2005, 51 (3-4) : 199 - 203
[2] Synthesis of calix[4] crowns containing soft donor atoms and a study of their metal-cation binding properties:: highly selective receptors for Cu2+
Ashram, M
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2002, (10): : 1662 - 1668
[3] MOLECULAR RECEPTORS - SYNTHESIS, X-RAY CRYSTAL-STRUCTURES, AND CHEMICAL-PROPERTIES OF CROWN ETHERS BEARING AN INTRAANNULAR PHENOLIC GROUP
BROWNE, CM
FERGUSON, G
MCKERVEY, MA
MULHOLLAND, DL
OCONNOR, T
PARVEZ, M
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (09) : 2703 - 2712
[4] Synthesis, X-ray structure and alkali-metal binding properties of a new hexahomotriazacalix[3]arene
Hampton, PD
Tong, WD
Wu, S
Duesler, EN
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (06): : 1127 - 1130
[5] Synthesis, X-ray crystal structure and optical properties of novel 1,3,5-triarylpyrazoline derivatives and the fluorescent sensor for Cu2+
Wang, Sheng-Qing
Gao, Ying
Wang, Hao-Yan
Zheng, Xiao-Xin
Shen, Shi-Li
Zhang, Yan-Ru
Zhao, Bao-Xiang
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 106 : 110 - 117
[6] Synthesis, reactivity, catenation and X-ray crystallography of Ag+ and Cu+ complexes of anthraquinone-based selenoethers: A luminescent chemodosimeter for Cu2+ and Fe3+
Mariappan, Kadarkaraisamy
Basa, Prem Nath
Balasubramanian, Vinothini
Fuoss, Sarah
Sykes, Andrew G.
POLYHEDRON, 2013, 55 : 144 - 154
[7] 2,3-Ethylene-bridged dihomooxacalix[4]arenes: synthesis, X-ray crystal structures and highly selective binding properties with anions
An, Lin
Wang, Jia-wei
Wang, Chan
Zhou, Shan-shan
Sun, Jing
Yan, Chao-Guo
NEW JOURNAL OF CHEMISTRY, 2018, 42 (13) : 10689 - 10696
[8] Synthesis, X-ray crystal structure and complexation properties towards metal ions of new thiacalix[4]arenes
Lamartine, R
Bavoux, C
Vocanson, F
Martin, A
Senlis, G
Perrin, M
TETRAHEDRON LETTERS, 2001, 42 (06) : 1021 - 1024
[9] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A NEW PALLADIUM CATALYST PRECURSOR CONTAINING AN ETA-2-PHOSPHINATE
LEONI, P
MARCHETTI, F
PASQUALI, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) : C25 - C27
[10] Synthesis of a new binucleating ligand and its binuclear Cu(II) complex: X-ray crystal structure, spectral and electrochemical properties
Rajendiran, TM
Venkatesan, R
Rao, PS
Kandaswamy, M
POLYHEDRON, 1998, 17 (19) : 3427 - 3432

← 1 2 3 4 5 →