Synthesis and Structure of Tetra- and Triarylantimony Oximates

被引：0
|
作者：
V. V. Sharutin
O. K. Sharutina
O. V. Molokova
E. N. Ettenko
D. B. Krivolapov
A. T. Gubaidullin
I. A. Litvinov
机构：
[1] Blagoveshchensk State Pedagogical University,
来源：
Russian Journal of General Chemistry | 2001年 / 71卷
关键词：
Oxygen; Hydrogen; Ether; Hydrogen Peroxide; Toluene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Pentaphenyl- and penta-p-tolylantimony were reacted with benzophenone oxime or triarylantimony bis(benzophenonoximate) in toluene to obtain tetraarylantimony benzophenonoximate. Triarylantimony bis(benzophenonoximates) were prepared by oxidative addition from tryarylstibine and oxime in ether in the presence of hydrogen peroxide. X-ray diffraction analysis of tetraphenylantimony benzophenonoximate was performed to show that coordination of the antimony atom is trigonal-bipyramidal and the oxime oxygen atom is axial.
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页码：1243 / 1247
页数：4
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