Core-modified octaphyrins: Syntheses and anion-binding properties

被引:0
作者
Rajneesh Misra
Venkataramanarao G Anand
Harapriya Rath
Tavarekere K Chandrashekar
机构
[1] Indian Institute of Technology,Department of Chemistry
[2] Regional Research Laboratory,undefined
关键词
Anion binding; aromaticity; 34; electrons; octaphyrin; oxidative coupling reactions;
D O I
10.1007/BF03356102
中图分类号
学科分类号
摘要
In this paper, a brief review of the syntheses, characterization and anion-binding properties of core-modified octaphyrins is presented. It has been shown that the core-modified octaphyrins exhibit aromaticity both in solution and in solid state, confirming the validity of the (4n + 2) Huckel rule for larger π-electron systems. Solid-state binding characteristics of TFA anions of two core-modified octaphyrins are also described.
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页码:99 / 103
页数:4
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