Oxidation of the iron(II) complex with 3,5-dimethylpyrazole by air in acetonitrile and dibenzyl ether

被引：0
|
作者：
E. V. Perova
S. E. Nefedov
D. G. Chikhichin
G. L. Kamalov
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] National Academy of Sciences of Ukraine,Bogatskii Physicochemical Institute
来源：
Russian Journal of Inorganic Chemistry | 2009年 / 54卷
关键词：
Benzaldehyde; Chloride Hexahydrate; Bridge Oxygen Atom; Dichloromethane Solution; Benzyl Benzoate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of the polymeric complex FeCl2(NCMe)2 (1) with 3,5-dimethylpyrazole (Hdmpz) yields the tetrahedral complex [Fe(Hdmpz)3Cl]Cl (2), which is oxidized by air in acetonitrile to give [Fe(Hdmpz)3Cl2]2(μ-O) (3). The reaction of FeCl3 · 6H2O with Hdmpz also leads to complex 3. The oxidation of complex 2 in a dichloromethane solution of dibenzyl ether gives the complex (Hdmpz)FeCl2[η2-N,O-(dmpz)C(O)H(Ph)] (4), which contains a coordinated tetrahedral intermediate product of condensation of Hdmpz and benzaldehyde. The structures of complexes 1–4 are discussed on the basis of X-ray crystallographic data.
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页码：1936 / 1946
页数：10
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