Latent ruthenium carbene complexes with six-membered N- and S-chelate rings

被引：0

作者：

N. M. Shcheglova

V. D. Kolesnik

R. V. Ashirov

E. A. Krasnokutskaya

机构：

[1] LLC NIOST,

[2] National Research Tomsk Polytechnic University,undefined

来源：

Russian Chemical Bulletin | 2016年 / 65卷

关键词：

metathesis; carbene complexes; ruthenium; catalyst; polymerization; dicyclopentadiene; polydicyclopentadiene;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

New ruthenium carbene complexes with chelating N- and S-benzylidene ligands were synthesized by the reactions of second- and third-generation Grubbs catalysts with ortho-vinylbenzyl-substituted amines or sulfides. These complexes were shown to exhibit catalytic activity in ring-opening metathesis polymerization and ring-closing metathesis.

引用

页码：490 / 497

页数：7

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