Latent ruthenium carbene complexes with six-membered N- and S-chelate rings

被引:0
|
作者
N. M. Shcheglova
V. D. Kolesnik
R. V. Ashirov
E. A. Krasnokutskaya
机构
[1] LLC NIOST,
[2] National Research Tomsk Polytechnic University,undefined
来源
Russian Chemical Bulletin | 2016年 / 65卷
关键词
metathesis; carbene complexes; ruthenium; catalyst; polymerization; dicyclopentadiene; polydicyclopentadiene;
D O I
暂无
中图分类号
学科分类号
摘要
New ruthenium carbene complexes with chelating N- and S-benzylidene ligands were synthesized by the reactions of second- and third-generation Grubbs catalysts with ortho-vinylbenzyl-substituted amines or sulfides. These complexes were shown to exhibit catalytic activity in ring-opening metathesis polymerization and ring-closing metathesis.
引用
收藏
页码:490 / 497
页数:7
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