Latent ruthenium carbene complexes with six-membered N- and S-chelate rings

被引：0
作者：
N. M. Shcheglova
V. D. Kolesnik
R. V. Ashirov
E. A. Krasnokutskaya
机构：
[1] LLC NIOST,
[2] National Research Tomsk Polytechnic University,undefined
来源：
Russian Chemical Bulletin | 2016年 / 65卷
关键词：
metathesis; carbene complexes; ruthenium; catalyst; polymerization; dicyclopentadiene; polydicyclopentadiene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New ruthenium carbene complexes with chelating N- and S-benzylidene ligands were synthesized by the reactions of second- and third-generation Grubbs catalysts with ortho-vinylbenzyl-substituted amines or sulfides. These complexes were shown to exhibit catalytic activity in ring-opening metathesis polymerization and ring-closing metathesis.
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页码：490 / 497
页数：7
相关论文
共 59 条
  • [1] Freitas E. R.(1979)undefined Chem. Eng. Prog. 75 73-76
  • [2] Gum C. R.(2002)undefined J. Mol. Catal. A: Chem. 190 65-2946
  • [3] Caster K. C.(2010)undefined Polymer 51 2927-2041
  • [4] Tokas E. F.(1995)undefined Angew. Chem., Int. Ed. 34 2039-137
  • [5] Keck C. G.(2009)undefined Nat. Chem. 1 133-3604
  • [6] Hontz M. E.(2006)undefined Organometallics 25 3599-5401
  • [7] Leitgeb A.(2004)undefined Organometallics 23 5399-2258
  • [8] Wappel J.(2005)undefined Organometallics 24 2255-6558
  • [9] Slugovc C.(2012)undefined Dalton Trans. 41 32-956
  • [10] Schwab P.(2010)undefined J. Org. Chem. 6 1106-1334
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