Densities, Excess Volumes, and Partial Molar Volumes of m-Xylene+Ethyl Acrylate, +Butyl Acrylate, +Methyl Methacrylate, and +Styrene at 298.15 K

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作者
R. D. Peralta
R. Infante
G. Cortez
G. Cadenas
J. Wisniak
机构
[1] Centro de Investigación en Química Aplicada,Department of Chemical Engineering
[2] Saltillo,undefined
[3] Ben-Gurion University of the Negev,undefined
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acrylates; densities; excess volumes; -xylene; monomers; styrene;
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摘要
Densities of the binary systems of m-xylene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene have been measured as a function of composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the binaries of m-xylene with methyl methacrylate, ethyl acrylate, and styrene. The excess volumes for the m-xylene+butyl acrylate system are positive for solvent (m-xylene) concentrations below 0.3 mole fraction and negative above this concentration.
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页码:1061 / 1071
页数:10
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