The Homogeneity Range of Crystalline Tris(8-hydroxyquinoline)gallium

被引：0
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作者：
A. A. Akkuzina
N. N. Kozlova
R. I. Avetisov
I. Kh. Avetisov
机构：
[1] Mendeleev University of Chemical Technology of Russia,
来源：
Doklady Chemistry | 2018年 / 480卷
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摘要：
An experimental procedure has been developed for constructing pi–T diagrams (partial vapor pressure of the ligand-forming component–temperature) for luminescent metal complexes with symmetric organic ligands. The partial 8-hydroxyquinoline vapor pressure–temperature diagram has been constructed for tris(8-hydroxyquinoline)gallium electrophosphor (Gaq3) in the temperature range 300–617 K at 8-hydroxyquinoline vapor pressures 10–3–104 Pa, where the homogeneity ranges of different Gaq3 polymorphs have been determined. Structure-sensitive properties of crystalline materials can be tailored by changing synthesis conditions within the homogeneity range of a phase.
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页码：85 / 88
页数：3
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