Habit of long-chain molecular crystals

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作者
V. M. Egorov
V. A. Marikhin
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[1] Russian Academy of Sciences,Ioffe Institute
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The quantitative analysis of the temperature dependence of the heat capacity of molecular crystals with chains of different lengths was performed using the theory of diffuse first-order phase transitions. The same chemical structure of the “core” of molecular crystals of {CH3(CH2)nCH3} normal paraffins, {COH(CH2)nCOH} diols, {CH3(CH2)nCOH} normal alcohols, and {CH3(CH2)nCOOH} saturated carboxylic and {COOH(CH2)nCOOH} dicarboxylic acids enabled the comparative analysis of phase transition parameters.
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页码:2353 / 2357
页数:4
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