Reactions of aqueous copper acetate with triethylamine and 3,5-dimethylpyrazole

被引：0
|
作者：
E. V. Perova
M. A. Yakovleva
E. O. Baranova
I. V. Anan’ev
S. E. Nefedov
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2010年 / 55卷
关键词：
Pyrazolate; Mother Liquor; Binuclear Complex; Carboxylate Anion; Copper Acetate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The dissolution of aqueous copper acetate in tetrahydrofuran gives the Cu2(μ-OOCMe)4(thf)2 complex (1), and its reaction with triethylamine in the presence of acetic acid yields “[Cu2(μ-OOCMe)4[μ-OOCMe(HNEt3)]”n polymer (2). Complexes 1 and 2 react with 3,5-dimethylpyrazole to form Cu(Hdmpz)2(OOCMe)2 (3) and Cu2(μ-OOCMe)4(Hdmpz)2 (4), respectively. The structures of complexes 1–4 and that of solvate 4 × 0.5C6H6 (5) are determined by X-ray diffraction.
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页码：714 / 726
页数：12
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