Reactions of aqueous copper acetate with triethylamine and 3,5-dimethylpyrazole

被引：0
|
作者：
E. V. Perova
M. A. Yakovleva
E. O. Baranova
I. V. Anan’ev
S. E. Nefedov
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2010年 / 55卷
关键词：
Pyrazolate; Mother Liquor; Binuclear Complex; Carboxylate Anion; Copper Acetate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The dissolution of aqueous copper acetate in tetrahydrofuran gives the Cu2(μ-OOCMe)4(thf)2 complex (1), and its reaction with triethylamine in the presence of acetic acid yields “[Cu2(μ-OOCMe)4[μ-OOCMe(HNEt3)]”n polymer (2). Complexes 1 and 2 react with 3,5-dimethylpyrazole to form Cu(Hdmpz)2(OOCMe)2 (3) and Cu2(μ-OOCMe)4(Hdmpz)2 (4), respectively. The structures of complexes 1–4 and that of solvate 4 × 0.5C6H6 (5) are determined by X-ray diffraction.
引用
收藏
页码：714 / 726
页数：12
相关论文
共 50 条
  • [1] Reactions of aqueous copper acetate with triethylamine and 3,5-dimethylpyrazole
    Perova, E. V.
    Yakovleva, M. A.
    Baranova, E. O.
    Anan'ev, I. V.
    Nefedov, S. E.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (05) : 714 - 726
  • [2] Dichlorobis(3,5-dimethylpyrazole)copper(II)
    Zhao, NF
    Eichhorn, DM
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M822 - M823
  • [3] Copper(II) trimethylacetate complexes with 3,5-dimethylpyrazole
    Denisova, T. O.
    Amel'chenkova, E. V.
    Pruss, I. V.
    Dobrokhotova, Zh. V.
    Fialkovskii, O. P.
    Nefedov, S. E.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (07) : 1020 - 1064
  • [4] Copper(II) trimethylacetate complexes with 3,5-dimethylpyrazole
    T. O. Denisova
    E. V. Amel’chenkova
    I. V. Pruss
    Zh. V. Dobrokhotova
    O. P. Fialkovskii
    S. E. Nefedov
    Russian Journal of Inorganic Chemistry, 2006, 51 : 1020 - 1064
  • [5] Aqua(3,5-dimethylpyrazole)(N-salicylideneglycinato)copper(II)
    Warda, SA
    Friebel, C
    Sivy, J
    Plesch, G
    Svajlenova, O
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 2763 - 2766
  • [6] Tris(3,5-dimethylpyrazole)copper(II) nitrate: as an oxidation catalyst
    Sharma, S
    Barooah, N
    Baruah, JB
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 229 (1-2) : 171 - 176
  • [7] N-(2-HYDROXYETHYL)-3,5-DIMETHYLPYRAZOLE, A DINUCLEAR COPPER COMPLEX, AND N-(2-p- TOLUENESULFONYLETHYL)-3,5-DIMETHYLPYRAZOLE
    Bouwman, E
    Driessen, WL
    Kang, J
    Darensbourg, MY
    INORGANIC SYNTHESES, VOL 32, 1998, 32 : 82 - 87
  • [8] 3,5-DIMETHYLPYRAZOLE (PYRAZOLE, 3,5-DIMETHYL-)
    WILEY, RH
    HEXNER, PE
    ORGANIC SYNTHESES, 1951, 31 : 43 - 44
  • [9] Syntheses and structural characterization of nine coordination compounds assembled from copper acetate, 3,5-dimethylpyrazole and carboxylates
    Jin, Shou-Wen
    Ye, Xiang-Hang
    Jin, Li
    Zheng, Lu
    Li, Jing-Wen
    Jin, Bin-Peng
    Wang, Da-Qi
    POLYHEDRON, 2014, 81 : 382 - 395
  • [10] STRUCTURE OF DICHLOROBIS(3,5-DIMETHYLPYRAZOLE)PALLADIUM
    CHENG, CH
    LAIN, JS
    WU, YJ
    WANG, SL
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 208 - 210
12345