Osmium(VIII)-Catalyzed Oxidation of Some Cyclic Amines by Potassium Hexacyanoferrate(III) in Alkaline Media: a Kinetics and Mechanistic Study

被引：0

作者：

M. M. Al-Subu

W. J. Jondi

A. A. Amer

M. Hannoun

M. J. Musmar

机构：

[1] An-Najah National University,Department of Chemistry

[2] College of Pharmacy,undefined

[3] An-Najah National University,undefined

来源：

Chemistry of Heterocyclic Compounds | 2003年 / 39卷 / 4期

关键词：

morpholine; piperidine; piperazine; Os(VIII); hexacyanoferrate(III); lactam; kinetics; oxidation;

D O I：

10.1023/A:1024765330259

中图分类号：

学科分类号：

摘要：

Reactions of morpholine, piperidine, and piperazine with Os(VIII)-catalyzed hexacyanoferrate(III) in alkaline media to produce the corresponding lactam have been studied at constant temperature and ionic strength. The reactions followed first-order kinetics with respect to [amine] and [Os(VIII)] but were independent of [Fe(CN)63-] and [OH-]. The effects of introduced electrolytes, potassium hexacyanoferrate(II), relative permitivity, and temperature have also been studied. A mechanism accounting for these results has been proposed.

引用

页码：478 / 484

页数：6

共 50 条

[41] Mechanistic studies of uncatalyzed and ruthenium(III)-catalyzed oxidation of the antibiotic drug chloramphenicol by hexacyanoferrate(III) in aqueous alkaline medium: a comparative kinetic study
M. D. Meti
K. S. Byadagi
S. T. Nandibewoor
S. A. Chimatadar
Monatshefte für Chemie - Chemical Monthly, 2014, 145 : 1561 - 1573
[42] Osmium(VIII) catalysed and uncatalysed oxidation of aspirin drug by diperiodatocuprate(III) complex in aqueous alkaline medium: A mechanistic approach
Hosamani, Ragunatharaddi R.
Mahesh, R. T.
Nandibewoor, Sharanappa T.
POLYHEDRON, 2010, 29 (05) : 1443 - 1452
[43] Kinetic, mechanistic and spectral investigations of ruthenium(III)/osmium(VIII)-catalysed oxidation of paracetamol by alkaline diperiodatoargentate(III) (stopped flow technique)
Sirsalmath, Kiran T.
Hiremath, Chanabasayya V.
Nandibewoor, Sharanappa T.
APPLIED CATALYSIS A-GENERAL, 2006, 305 (01) : 79 - 89
[44] Base-catalyzed oxidation of sulfated kappa-carrageenan by alkaline hexacyanoferrate(III): A mechanistic approach of electron-transfer process
Hassan, Refat M.
Ibrahim, Samia M.
JOURNAL OF MOLECULAR LIQUIDS, 2019, 273 : 177 - 182
[45] Kinetics and mechanism of the Os(VIII)-catalysed oxidation of hypophosphite and phenylphosphinite ion by alkaline hexacyanoferrate(III) ion
Sharma, Kamla
Mehrotra, Raj N.
POLYHEDRON, 2008, 27 (17) : 3425 - 3432
[46] Kinetic study of ruthenium (VI)-catalyzed oxidation of 2-propanol by alkaline hexacyanoferrate (III)
Mucientes, AE
Poblete, FJ
Rodríguez, MA
Santiago, F
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1999, 12 (12) : 901 - 908
[47] Osmium(VIII) Catalyzed Oxidation of DL-Ornithine Monohydrochloride by a New Oxidant, Diperiodatoargentate(III) in Aqueous Alkaline Medium
Malode, Shweta J.
Abbar, Jyothi C.
Nandibewoor, Sharanappa T.
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (04) : 246 - 256
[48] A kinetic study of iridium(III) chloride catalyzed oxidation of diethylene glycol by hexacyanoferrate(III) in aqueous alkaline medium
Goel, A
Chauhan, M
ASIAN JOURNAL OF CHEMISTRY, 2004, 16 (02) : 1200 - 1202
[49] Spectroscopic investigation and oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media: a mechanistic approach
Meti, Manjunath
Nandibewoor, Sharanappa
Chimatadar, Shivamurti
TURKISH JOURNAL OF CHEMISTRY, 2014, 38 (03) : 477 - 487
[50] Kinetics and mechanism of the ruthernium(III) catalyzed oxidation of propane-1,3-diol by alkaline hexacyanoferrate(III)
A. E. Mucientes
F. J. Poblete
F. Santiago
J. Casado
Reaction Kinetics and Catalysis Letters, 1997, 62 : 293 - 297

← 1 2 3 4 5 →