Osmium(VIII)-Catalyzed Oxidation of Some Cyclic Amines by Potassium Hexacyanoferrate(III) in Alkaline Media: a Kinetics and Mechanistic Study

被引：0
|
作者：
M. M. Al-Subu
W. J. Jondi
A. A. Amer
M. Hannoun
M. J. Musmar
机构：
[1] An-Najah National University,Department of Chemistry
[2] College of Pharmacy,undefined
[3] An-Najah National University,undefined
来源：
Chemistry of Heterocyclic Compounds | 2003年 / 39卷 / 4期
关键词：
morpholine; piperidine; piperazine; Os(VIII); hexacyanoferrate(III); lactam; kinetics; oxidation;
D O I：
10.1023/A:1024765330259
中图分类号：
学科分类号：
摘要：
Reactions of morpholine, piperidine, and piperazine with Os(VIII)-catalyzed hexacyanoferrate(III) in alkaline media to produce the corresponding lactam have been studied at constant temperature and ionic strength. The reactions followed first-order kinetics with respect to [amine] and [Os(VIII)] but were independent of [Fe(CN)63-] and [OH-]. The effects of introduced electrolytes, potassium hexacyanoferrate(II), relative permitivity, and temperature have also been studied. A mechanism accounting for these results has been proposed.
引用
收藏
页码：478 / 484
页数：6
相关论文
共 50 条
  • [1] Osmium(VIII) - Catalyzed oxidation of some cyclic amines by potassium hexacyanoferrate(III) in alkaline media: A kinetics and mechanistic study
    Al-Subu, MM
    Jondi, WJ
    Amer, AA
    Hannoun, M
    Musmar, MJ
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2003, (04): : 559 - 565
  • [2] Mechanistic Studies of Osmium(VIII) Catalysed Oxidation of Sulfanilic Acid by Hexacyanoferrate (III) in Alkaline Medium
    Sairabanu A. Farokhi
    Sharanappa T. Nandibewoor
    Catalysis Letters, 2009, 129 : 207 - 214
  • [3] Mechanistic Studies of Osmium(VIII) Catalysed Oxidation of Sulfanilic Acid by Hexacyanoferrate (III) in Alkaline Medium
    Farokhi, Sairabanu A.
    Nandibewoor, Sharanappa T.
    CATALYSIS LETTERS, 2009, 129 (1-2) : 207 - 214
  • [4] Osmium(VIII) catalyzed oxidation of an antibiotic drug chloramphenicol by hexacyanoferrate(III) in aqueous alkaline medium: A mechanistic approach
    Budri, Mahantesh B.
    Mangalgatti, Zahiruddin A.
    Hullur, Megharaj B.
    Meti, Manjunath D.
    Nandibewoor, Sharanappa T.
    Chimatadar, Shivamurti A.
    MAIN GROUP CHEMISTRY, 2013, 12 (01) : 1 - 14
  • [5] Kinetics and mechanism of osmium(VIII)-catalyzed oxidation of 1,4-thioxane by alkaline hexacyanoferrate(III)
    Mohammed M. Al-Subu
    Transition Metal Chemistry, 2001, 26 : 461 - 464
  • [6] Kinetics and mechanism of osmium(VIII)-catalyzed oxidation of hypophosphite by hexacyanoferrate(III) in aqueous alkali
    Dubey, S
    Sharma, N
    Khandelwal, CL
    Sharma, PD
    TRANSITION METAL CHEMISTRY, 2003, 28 (02) : 176 - 181
  • [7] Kinetics and mechanism of osmium(VIII)-catalyzed oxidation of hypophosphite by hexacyanoferrate(III) in aqueous alkali
    Sapna Dubey
    Neetu Sharma
    Chandra L. Khandelwal
    Prem D. Sharma
    Transition Metal Chemistry, 2003, 28 : 176 - 181
  • [8] A kinetic and mechanistic study of the osmium(VIII)-catalysed oxidation of crotyl alcohol by hexacyanoferrate(III) in aqueous Alkaline medium
    Sharma, Priyamvada
    Sailani, Riya
    Meena, Anita
    Khandelwal, Chandra Lata
    JOURNAL OF CHEMICAL RESEARCH, 2020, 44 (5-6) : 295 - 300
  • [9] KINETICS OF OXIDATION OF TRYPTOPHAN BY POTASSIUM HEXACYANOFERRATE(III) IN ALKALINE MEDIUM
    Laloo, D.
    Mahanti, M. K.
    OXIDATION COMMUNICATIONS, 2010, 33 (02): : 424 - 429
  • [10] Oxidation of some hydroxy acids by alkaline hexacyanoferrate(III) catalysed by ruthenium(VIII)
    Tandon, PK
    Singh, AK
    Baboo, R
    Kumar, S
    Saxena, AK
    Singh, MP
    OXIDATION COMMUNICATIONS, 2005, 28 (03): : 611 - 620
12345