We have studied refractive index dispersion in thin ZnGa2O4 films obtained by high-frequency RF ion plasma sputtering. We have established that the spectral dependence of the refractive index in the visible region of the spectrum is mainly determined by transitions from the band including 2p states of the oxygen and 3d states of the zinc, forming the highest occupied level of the valance band, to the bottom of the conduction band formed by the 4s4p states of the zinc. For the studied films, we have determined the parameters of the single-oscillator approximation, the dispersion energy, the chemical bond ionicity, and the coordination number.
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Univ Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, BrazilUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
de Sousa Filho, Idio Alves
Figueiredo, Jose Fernando Dagnone
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Univ Rennes, CNRS, UMR 6226, ISCR, F-35000 Rennes, France
Univ Fed Rural Pernambuco, BR-52171900 Cabo De Santo Agostinho, PE, BrazilUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
Figueiredo, Jose Fernando Dagnone
Bouquet, Valerie
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Univ Rennes, CNRS, UMR 6226, ISCR, F-35000 Rennes, FranceUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
Bouquet, Valerie
de Oliveira, Andre Luiz Menezes
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Univ Rennes, CNRS, UMR 6226, ISCR, F-35000 Rennes, France
Univ Fed Paraiba, Dept Quim, NPE, LACOM, Campus 1, BR-58059900 Joao Pessoa, PB, BrazilUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
de Oliveira, Andre Luiz Menezes
Lebullenger, Ronan
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Univ Rennes, CNRS, UMR 6226, ISCR, F-35000 Rennes, FranceUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
Lebullenger, Ronan
Santos, Ieda Maria Garcia
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机构:Univ Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
Santos, Ieda Maria Garcia
Guilloux-Viry, Maryline
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Univ Rennes, CNRS, UMR 6226, ISCR, F-35000 Rennes, FranceUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
Guilloux-Viry, Maryline
Merdrignac-Conanec, Odile
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Univ Rennes, CNRS, UMR 6226, ISCR, F-35000 Rennes, FranceUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil
Merdrignac-Conanec, Odile
Weber, Ingrid Tavora
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Univ Brasilia, Inst Quim, BR-70910900 Brasilia, DF, Brazil
Univ Fed Pernambuco, LIMC, Dept Quim Fundamental, BR-50740560 Recife, PE, BrazilUniv Fed Rural Rio Janeiro, QuiARA, Inst Quim, BR-23897000 Seropedica, RJ, Brazil