Ferrocene Macrocyclic Schiff Base Complex: Synthesis, Structure and Recognition Properties for Dual Hg2+ and Cu2+

被引：0
|
作者：
Xiaoju Liu
Yulin Xiang
Xiangrong Ma
Guoyu Ren
Liguo Gao
机构：
[1] Yu-Lin University of Yulin,Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute
来源：
Russian Journal of General Chemistry | 2017年 / 87卷
关键词：
ferrocene; ion recognition; fluorescence sensor; Hg; and Cu; cation sensing;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A probe based on ferrocene structure has been designed, synthesized and elucidated from the single crystal X-ray method. It demonstrated fluorescence response to Hg2+ and Cu2+ in CH3OH. The results indicated that the title complex could be applied in the multianalyte detection. Binding ability of receptor 3 in CH3OH was tested for various cations (Fe3+, Co2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, and Ba2+ in water). The computed binding constants for Hg2+ and Cu2+ indicated a distinct absorbance shift. The receptor is an attractive array due to its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in biology, environmental sciences and material chemistry.
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页码：2986 / 2988
页数：2
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