Synthesis and thermal behaviors of 1,3-bis(4-aminophenoxy)benzene (TPER) and polyimide based on TPER and pyromellitic dianhydride

被引：0
作者：
Jiao-Qiang Zhang
Hong-Xu Gao
Tie-Zheng Ji
Min Chao
Hai-Xia Ma
Kang-Zhen Xu
Rong-Zu Hu
机构：
[1] Northwestern Polytechnical University,Department of Applied Chemistry, Key Laboratory of Applied Physics and Chemistry in Space, Ministry of Education, School of Science
[2] Xi’an Modern Chemistry Institute,College of Chemical Engineering/Shaanxi Key Laboratory of Physico
[3] Northwest University,Inorganic Chemistry
来源：
Journal of Thermal Analysis and Calorimetry | 2013年 / 114卷
关键词：
1,3-Bis(4-aminophenoxy)benzene; Polyimide; Thermodynamic; Thermokinetic;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
1,3-Bis(4-aminophenoxy)benzene (TPER) and poly(amic acid) based on TPER and pyromellitic dianhydride (PMDA) were synthesized. After imidization of the poly(amic acid), polyimide based on TPER and PMDA was obtained. The melting process and the specific heat capacity (Cp) of TPER were examined by DSC and microcalorimetry, respectively. The melting enthalpy, the melting entropy, and the Cp for TPER were obtained. The enthalpy change, the entropy change, and the Gibbs free energy change for TPER were obtained within 283 and 353 K. The thermal decomposition reaction mechanism of the polyimide is classified from the TG–DTG experimental data, and the thermokinetic parameters of the thermal decomposition reaction are Ea = 296.87 kJ mol−1and log (A/s−1) = 14.41.
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页码：441 / 449
页数：8
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