[Na4(H2O)7][Fe(OH)6Mo6O18]: A new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center

被引：0
|
作者：
Chuande Wu
Xiang Lin
Rongmin Yu
Wenbin Yang
Canzhong Lu
Honghui Zhuang
机构：
[1] Fujian Institute of Research on the Structure of Matter,State Key Laboratory of Structural Chemistry
[2] Chinese Academy of Sciences,undefined
来源：
Science in China Series B: Chemistry | 2001年 / 44卷
关键词：
[12] metallacrown-6 structure; ring-shaped cluster; three-dimensional network; ESR;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (∼0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, [Na4(H2O)7][Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions.
引用
收藏
页码：49 / 54
页数：5
相关论文
共 7 条
  • [1] [Na4（H2O）7][Fe（OH）6Mo6O18]: a new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center
    吴传德
    林祥
    余荣民
    杨文斌
    卢灿忠
    庄鸿辉
    Science in China(Series B), 2001, (01) : 49 - 54
  • [2] [Na4(H2O)7][Pe(OH)6Mo6O18]:: a new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center
    Wu, C
    Lin, X
    Yu, RM
    Yang, WB
    Lu, CZ
    Zhuang, HH
    SCIENCE IN CHINA SERIES B-CHEMISTRY, 2001, 44 (01): : 49 - 54
  • [3] Synthesis and structure assignment of vanadyl(IV) citrate [(VO)3(C6H5O7)2]•H2O
    Baklanova, Inna, V
    Zhuravlev, Viktor D.
    Tyutyunnik, Alexander P.
    Melkozerova, Marina A.
    Patrusheva, Tatyana A.
    MENDELEEV COMMUNICATIONS, 2021, 31 (05) : 723 - 725
  • [4] CIS-/TRANS-ISOMERISM OF BIS-(TRISALKOXY)-HEXAVANADATES - CIS-NA-2[V-6(IV)O-7(OH)(6)((OCH2)(3)CCH2OH)(2))-CENTER-DOT-8H(2)O, CIS-(CN3H6)3[V-5(IV)O-V(13)((OCH2)(3)CCH2OH)(2)]-CENTER-DOT-4,5H(2)O AND TRANS-(CN3H6)(2)[V-6(V)O-13((OCH2)(3)CCH2OH)(2)]-CENTER-DOT-H2O
    MULLER, A
    MEYER, J
    BOGGE, H
    STAMMLER, A
    BOTAR, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (11): : 1818 - 1831
  • [5] Synthesis, structure and properties of a novel coordination polymer having three-dimensional networks [Nd(C7H6NO2)3•H2O]n
    Niu, SY
    Zhang, YL
    Lai, W
    Yang, ZZ
    Yang, GD
    Ye, L
    ACTA CHIMICA SINICA, 2001, 59 (12) : 2170 - 2175
  • [6] Hydrothermal synthesis, crystal structure and magnetism of [Nd(C7H6NO2)3•H2O]n, a novel coordination polymer with three-dimensional network
    Niu, SY
    Yang, GD
    Zhang, YL
    Jin, J
    Ye, L
    Yang, ZZ
    JOURNAL OF MOLECULAR STRUCTURE, 2002, 608 (01) : 95 - 99
  • [7] A novel supramolecular compound with three-dimensional hydrogen-bonded network [Hbet]3[Fe(CN)6]•4H2O:: synthesis, characterization and crystal structure
    Yan, B
    Wang, HD
    Chen, ZD
    JOURNAL OF MOLECULAR STRUCTURE, 2001, 569 (1-3) : 65 - 70
1