Spiro indane-based phosphine–oxazoline ligands for palladium-catalyzed asymmetric arylation of cyclic N-sulfonyl imines

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作者
Zhongxuan Qiu
Yanshun Li
Zhenqing Zhang
Dawei Teng
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[1] Qingdao University of Science and Technology,State Key Laboratory Base of Eco
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摘要
Palladium complexes of indane-based phosphine–oxazoline ligands with a spirocarbon stereogenic center were examined for asymmetric addition of arylboronic acids to cyclic N-sulfonyl imines. Excellent reaction activities (up to 99% yield) and enantioselectivities (up to 99% ee) were obtained with a broad scope of substrate.
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页码:649 / 654
页数:5
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