Synthesis and Structural Characterisation of Two Copper(II) Complexes of N-(1-acetyl-2-propylidene) (2-pyridylmethyl) amine

被引：0
作者：
Ruma Karmakar
Chirantan Roy Choudhury
Andrei S. Batsanov
Stuart R. Batten
Samiran Mitra
机构：
[1] Jadavpur University,Department of Chemistry
[2] University of Durham,Department of Chemistry
[3] Monash University,School of Chemistry
来源：
Structural Chemistry | 2005年 / 16卷
关键词：
Crystal structure; copper(II); tetradentate Schiff base; bromide; isocyanate;
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学科分类号：
摘要：
Two new complexes [CuBr(C11H13N2O)] (1) and [Cu(NCO)(C11H13N2O)] (2) containing the tridentate Schiff base ligand, N-(1-acetyl-2-propylidene)(2-pyridylmethyl) amine which is the 1:1 condensation product of acetylacetone and 2-aminomethylpyridine, have been synthesised and characterised by elemental analysis, IR and electronic spectra, electrochemical study and single crystal X-ray diffraction study. Crystal structures reveal that the copper atom in both the complexes are in square geometry formed by the N2O donor set of the Schiff base and a bromine atom in 1 and one cyanate ligand in 2. Both bromide and isocyanate ligands act in a terminal monodentate fashion.
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页码：535 / 539
页数：4
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