Copolymerization of N-vinylpyrrole-2-carbaldehydes with styrene, N-vinylpyrrolidone, and ethylene glycol vinyl glycidyl ether

被引：0
|
作者：
I. V. Tatarinova
L. V. Morozova
M. V. Markova
A. M. Vasil’tsov
A. V. Ivanov
G. F. Myachina
S. S. Khutsishvili
A. I. Mikhaleva
B. A. Trofimov
机构：
[1] Russian Academy of Sciences,Favorsky Institute of Chemistry, Siberian Branch
来源：
Polymer Science Series B | 2011年 / 53卷
关键词：
Copolymerization; Polymer Science Series; AIBN; Paramagnetic Center; Turbidimetric Titration;
D O I：
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中图分类号：
学科分类号：
摘要：
Polyfunctional reactive copolymers of N-vinylpyrrole-2-carbaldehydes with styrene, N-vinylpyrrolidone, and ethylene glycol vinyl glycidyl ether are synthesized in the presence of AIBN (2 wt %, 80°C, 50 h) with a yield of up to 98% and a molecular mass of up to 4800. The copolymers show paramagnetic behavior (N = 2.0 × 1015−2.0 × 1017 g−1) and possess the properties of organic semiconductors (σ = 0.9 × 10−11–2.8 × 10−7 S/cm after doping with I2).
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页码：125 / 131
页数：6
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