A family of crystal structures with [Pb3(OH)4Co(NO2)3]2+ cations

被引：0
|
作者：
S. P. Khranenko
N. V. Kuratieva
S. A. Gromilov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk National Research State University,undefined
来源：
Journal of Structural Chemistry | 2016年 / 57卷
关键词：
lead; cobalt; complex; single crystal X-ray diffraction study; powder X-ray diffraction study; crystal chemistry;
D O I：
暂无
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学科分类号：
摘要：
The structure of two crystalline modifications of [Pb3(OH)4Co(NO2)3](NO2)2 containing tetrahedral [Pb3(OH)4Co(NO2)3]2+ complex cations is studied. Three lead atoms and one cobalt atom are located in the vertices of a distorted tetrahedron with the edges of 3.39-3.92 Å. The distances from the metal atoms to the oxygen atoms belonging to μ3 bridging hydroxo groups are within 1.910-1.956 Å for Co–O and 2.340-2.439 Å for Pb–O. The packing motifs of the crystal structures are analyzed.
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页码：1044 / 1048
页数：4
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