Electrocatalytic oxidation and determination of estradiol using an electrode modified with carbon nanotubes and an ionic liquid

被引：0
作者：
Han Tao
Wanzhi Wei
Xiandong Zeng
Xiaoying Liu
Xuejun Zhang
Yiming Zhang
机构：
[1] Guizhou University,Province Key Laboratory of Fermentation Engineering and Biopharmaceutical, College of Chemistry and Chemical Engineering
[2] Hunan University,State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering
来源：
Microchimica Acta | 2009年 / 166卷
关键词：
Estradiol; MWNTs; Electrocatalysis; Ionic liquid;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A sensitive method for the determination of estradiol is presented that is based on an electrode modified with multi-walled carbon nanotubes (MWNTs) along with an ionic liquid. The resulting electrode showed more sensitive voltammetric response to estradiol than other electrodes modified with MWNTs. The peak current for estradiol is linearly related to concentration over two decades, and the limit of detection is 5 nM. The method was applied to the determination of estradiol in rabbit blood serum and in environmental waters. The recoveries were 95.3–104.0% and 97.0–104.7%, respectively.
引用
收藏
页码：53 / 59
页数：6
相关论文
共 165 条
[21]  
Zhai XR(2008)Effects of larval exposure to estradiol on spermatogenesis and in vitro gonadal steroid secretion in African clawed frogs, Xenopus laevis Gen Comp Endocrinol 71 155-undefined
[22]  
Zeng JX(2005)Estradiol and endocrine disrupting compounds adversely affect development of sea urchin embryos at environmentally relevant concentrations Aquat Toxicol 3 491-undefined
[23]  
Yi HC(1970)Gas chromatographic determination of estrone, estradiol and estriol in non-pregnancy plasma Mikroehimica Acta 78 442-undefined
[24]  
Qu WY(2009)Molecularly imprinted solid-phase extraction for the selective determination of 17β-estradiol in fishery samples with high performance liquid chromatography Talanta 627 277-undefined
[25]  
Huang WS(2008)Determination of estradiol in human serum using magnetic particles-based chemiluminescence immunoassay Anal Chim Acta 632 128-undefined
[26]  
Fukushima T(2009)Simultaneous detection for three kinds of veterinary drugs: chloramphenicol, clenbuterol and 17-beta-estradiol by high-throughput suspension array technology Anal Chim Acta 133 381-undefined
[27]  
Kosaka A(2008)A sensitive nonenzymatic hydrogen peroxide sensor based on DNA-Cu Sense Actuators B 28 753-undefined
[28]  
Ishimura Y(2002) complex electrodeposition onto glassy carbon electrode Pharm Biomed Anal 22 895-undefined
[29]  
Yamamoto T(2006)Voltammetric investigation of β-estradiol Anal Sci 22 253-undefined
[30]  
Takigawa T(2006)Voltammetric behavior and determination of 17β-estradiol at multi-Wall carbon nanotube-nafion modified glassy carbon electrode Biosens Bioelectron 594 184-undefined
12345678910