Kinetics of the reaction between boron trifluoride methanol complex and sodium methoxide to produce enriched 10B methylborate

被引：0

作者：

Lang W. ^{[1
,2
]}

Zhang W. ^{[1
]}

Tang Y. ^{[1
]}

Xu J. ^{[1
]}

Zhang L. ^{[3
]}

机构：

[1] School of Chemical Engineering and Technology, Tianjin University, Tianjin

[2] College of Chemistry and Life Science, Weinan Normal University, Weinan

[3] School of Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang

来源：

Transactions of Tianjin University | 2016年 / 22卷 / 02期

关键词：

boron trifluoride methanol complex; conductivity; kinetics; sodium methoxide;

D O I：

10.1007/s12209-016-2661-7

中图分类号：

学科分类号：

摘要：

The relation of boron trifluoride concentration with conductivity in boron trifluoride methanol solution (BF3-CH3OH)was power exponent fitted in low concentration range. The kinetics of the reaction between boron trifluoride methanol complex and sodium methoxide to produce enriched 10B methylborate was proposed based on a detailed mechanism study, and was verified by acid-base titration method and conductivity method. It was found that this reaction is first order reaction and the rate constant is 0.022 min−1 at 338 K(65 °C), the activity energy is 65 kJ/mol. In addition, it was found that the conductivity method is more feasible to measure the kinetic curve than acid-base titration method. © 2016, Tianjin University and Springer-Verlag Berlin Heidelberg.

引用

页码：139 / 143

页数：4

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