Synthesis and crystal structure of [Mo3S4(Dppen)3Cl3]PF6 · 1.5CH2Cl2 and [W3S4(Dppe)3Br3]2ZnBr4 · 5.5CH3CN

被引：0
作者：
S. A. Adonin
P. A. Abramov
A. V. Virovets
M. N. Sokolov
V. P. Fedin
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Russian Journal of Coordination Chemistry | 2010年 / 36卷
关键词：
Dppe; Diphosphine; Cluster Cation; Diphosphine Ligand; Dmpe;
D O I：
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摘要：
New cluster complexes [Mo3S4(Dppen)3Cl3]PF6 · 1.5CH2Cl2 (Dppen = cis-Ph2PCH=CHPPh2) (I) and [W3S4(Dppe)3Br3]2(ZnBr4)2 · 5.5CH3CN (Dppe = Ph2PCH2CH2PPh2) (II) were synthesized. Their molecular and crystal structures were determined by X-ray diffraction. Diphoshine ligands in the complexes I and II are coordinated in the bidentate mode, providing an arrangement of three chelate rings, giving rise to chirality.
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页码：637 / 643
页数：6
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