High Temperature Oxidation Performance of an Additively Manufactured Mo–9Si–8B Alloy

As reported in previous studies, the processing of Mo–Si–B alloys using additive manufacturing (AM) techniques, like directed energy deposition (DED) shows a high technical feasibility. The present work investigates the cyclic oxidation performance of an AM DED Mo–9Si–8B alloy. Depending on the temperature (800 °C, 1100 °C, 1300 °C), the oxidation mechanisms vary, which is due to different reactions at the surface of the alloys accompanied with mass changes of samples. These mass changes can be explained on the basis of microstructural investigations. However, compared to a powder metallurgically processed Mo–9Si–8B alloy, the AM-DED alloy shows competitive oxidation performance at potential application temperatures of 1100 °C and 1300 °C, while a catastrophic materials degradation occurs at 800 °C as also observed in other Mo-rich Mo–Si–B alloys.