Reactivity of Radical Cations of Trimesitylphosphine

被引：0
|
作者：
V. A. Zagumennov
E. V. Nikitin
机构：
[1] Kazan State University,
来源：
Russian Journal of Electrochemistry | 2003年 / 39卷
关键词：
radical cation; reactivity; trimesitylphosphine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Anodic oxidation of trimesitylphosphine in the presence of typical nucleophilic reactants is studied by cyclic voltammetry. The results and the literature data suggest that the manifestation of radical properties is more typical for radical cations of trimesitylphosphine, because, when realizing an electrophilic path of reacting, additional energy is needed for altering the configuration of radical cations of trimesitylphosphine.
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页码：1236 / 1239
页数：3
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