Stable UV absorption material synthesized by intercalation of squaric acid anion into layered double hydroxides

被引:0
作者
Shi-Feng Li
Yan-Ming Shen
Min Xiao
Zhi-Gang Zhang
Wen-Xiu Li
机构
[1] Shenyang University of Chemical Technology,Liaoning Provincial Key Laboratory of Chemical Separation Technology
[2] Shenyang University,College of Environment
来源
Chemical Papers | 2015年 / 69卷
关键词
UV absorber; squaric acid; intercalation; layered double hydroxides;
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摘要
A novel UV absorption material of squaric acid (SA) anion (O4O42−) intercalated layered double hydroxides (LDHs) was successfully synthesized by the co-precipitation method. After intercalation, the interlayer distance of MgAl-SA-LDHs increased to 1.04 nm compared to those of MgAl-CO3-LDHs and SA anions present in form of a monolayer in the interlayer of LDHs. Thermal stability of SA clearly enhanced by the intercalation and the suppression of the deintercalation ability of MgAl-SA-LDHs was superior to that of 4-hydroxy-3-methoxybenzoic acid intercalated LDHs. The results of UV-DRS indicate the potential application of MgAl-SA-LDHs as UV absorbers.
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页码:456 / 461
页数:5
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