Structure of the framework complex K0.4Cs0.6{Cd(H2O)2Re6S8(CN)4(OH)(H2O)}•8H2O

被引：0
作者：
A. Yu. Ledneva
A. V. Virovets
N. G. Naumov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk National Research State University,undefined
来源：
Journal of Structural Chemistry | 2015年 / 56卷
关键词：
synthesis; rhenium; octahedral cluster; cadmium; synthesis; topological crystal chemistry; hydrogen bond;
D O I：
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学科分类号：
摘要：
By single crystal X-ray diffraction, the structure of a new compound based on octahedral mixed-ligand anionic cluster complexes of rhenium and cadmium(II) cations is determined: K0.4Cs0.6{Cd(H2O)2Re6S8(CN)4(OH)(H2O)}•8H2O (1). The compound has a framework structure with a pts (platinum sulfide) topology. The cluster anions are additionally chained together by strong OH⋯H2O hydrogen bonds between the terminal ligands of neighboring clusters; the O⋯O distance is 2.464 Å.
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页码：1024 / 1027
页数：3
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