Tetraphenylantimony(V) O,O′-dialkyl dithiophosphates [Sb(C6H5)4{S2P(OR)2}] (R = s-C4H9, c-C6H11): Synthesis, structures, and 13C and 31P CP/MAS NMR spectra

被引：0
|
作者：
M. A. Ivanov
V. V. Sharutin
A. V. Ivanov
A. V. Gerasimenko
O. N. Antsutkin
机构：
[1] Russian Academy of Sciences,Institute of Geology and Nature Management, Amur Scientific Center, Far East Division
[2] Blagoveshchensk State Pedagogical University,Institute of Chemistry, Far East Division
[3] Russian Academy of Sciences,undefined
[4] Luleå University of Technology,undefined
来源：
Russian Journal of Coordination Chemistry | 2008年 / 34卷
关键词：
Coordination Chemistry; Trigonal Bipyramid; Bidentate Coordination; Antimonite; Chemical Shift Tensor;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Tetraphenylantimony(V) O,O′-di-sec-butyl dithiophosphate (I) and tetraphenylantimony(V) O,O′-dicyclohexyl dithiophosphate (II) [Sb(C6H5)4{S2P(OR)2}] (R = sec-C4H9 or cyclo-C6H11) were obtained. Their structures and spectroscopic properties were studied by X-ray diffraction analysis and 13C and 31P CP/MAS NMR spectroscopy. The dithiophosphate (Dtph) ligands in complexes I and II were found to be coordinated in S-monodentate and S,S′-bidentate fashions, respectively (MAS NMR data). According to X-ray diffraction data, the coordination polyhedron of antimony in molecular structure I is a trigonal bipyramid with unusual monodentate coordination of the Dtph group in the axial position.
引用
收藏
页码：527 / 535
页数：8
相关论文
共 50 条
  • [1] Tetraphenylantimony(V) O,O′-dialkyl dithiophosphates [Sb(C6H5)4{S2P(OR)2}] (R = s-C4H9, c-C6H11):: Synthesis, structures, and 13C and 31P CP/MAS NMR spectra
    Ivanov, M. A.
    Sharutin, V. V.
    Ivanova, A. V.
    Gerasimenko, A. V.
    Antsutkind, O. N.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (07) : 527 - 535
  • [2] Synthesis, structure, and 13C and 31P CP/MAS NMR of the tetraphenylantimony(V) di-iso-propyl phosphorodithioate complex [Sb(C6H5)4{S2P(O-iso-C3H7)2}] and its solvated form [Sb(C6H5)4{S2P(O-iso-C3H7)2}] • 1/2C6H6: An example of the monodentate coordination of dithio ligands
    Ivanov, M. A.
    Sharutin, V. V.
    Ivanov, A. V.
    Gerasimenko, A. V.
    Antzutkin, O. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (05) : 708 - 716
  • [3] Synthesis, structure, and 13C and 31P CP/MAS NMR of the tetraphenylantimony(V) di-iso-propyl phosphorodithioate complex [Sb(C6H5)4{S2P(O-iso-C3H7)2}] and its solvated form [Sb(C6H5)4{S2P(O-iso-C3H7)2}] · 1/2C6H6: An example of the monodentate coordination of dithio ligands
    M. A. Ivanov
    V. V. Sharutin
    A. V. Ivanov
    A. V. Gerasimenko
    O. N. Antzutkin
    Russian Journal of Inorganic Chemistry, 2009, 54 : 708 - 716
  • [4] The diethyl dithiophosphate complex of tetraphenylantimony(V) and its solvated form, [Sb(C6H5)4{S2P(OC2H5)2}] • 1/2 C6H6: Synthesis, crystal structure, and 13C, 31P CP/MAS NMR study. an example of monodentate coordination of dithio ligands
    Ivanov, M. A.
    Gerasimenko, A. V.
    Ivanov, A. V.
    Solozhenkin, P. M.
    Sharutin, V. V.
    Larsson, A. -C.
    Antzutkin, O. N.
    Pushilin, M. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (02) : 197 - 205
  • [5] The diethyl dithiophosphate complex of tetraphenylantimony(V) and its solvated form, [Sb(C6H5)4{S2P(OC2H5)2}] · 1/2 C6H6: Synthesis, crystal structure, and 13C, 31P CP/MAS NMR study. an example of monodentate coordination of dithio ligands
    M. A. Ivanov
    A. V. Gerasimenko
    A. V. Ivanov
    P. M. Solozhenkin
    V. V. Sharutin
    A. -C. Larsson
    O. N. Antzutkin
    M. A. Pushilin
    Russian Journal of Inorganic Chemistry, 2013, 58 : 197 - 205
  • [6] (C6H5)2P-SB(C6H5)2 AND (C6H5)2AS-SB(C6H5)2
    KUHN, N
    WINTER, M
    CHEMIKER-ZEITUNG, 1983, 107 (11): : 342 - 342
  • [7] Synthesis, structure, and 13C and 31P CP/MAS NMR of crystalline modifications of the polynuclear thallium(I) O,O′-dicyclohexyl phosphorodithioate complex [Tl{S2P(O-cyclo-C6H11)2}]n
    T. A. Rodina
    A. V. Ivanov
    V. A. Konfederatov
    V. I. Mitrofanova
    A. V. Gerasimenko
    O. N. Antzutkin
    Russian Journal of Inorganic Chemistry, 2009, 54 : 1779 - 1788
  • [8] Synthesis, structure, and 13C and 31P CP/MAS NMR of crystalline modifications of the polynuclear thallium(I) O,O'-dicyclohexyl phosphorodithioate complex [Tl{S2P(O-cyclo-C6H11)2}] n
    Rodina, T. A.
    Ivanov, A. V.
    Konfederatov, V. A.
    Mitrofanova, V. I.
    Gerasimenko, A. V.
    Antzutkin, O. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (11) : 1779 - 1788
  • [9] Synthesis and characterization of organophosphoryl polyoxotungstate [α2-R2P2W17O61]6- (R = C6H11P(O), C6H5P(O), C6H11P(S), C6H5P(S))
    Sun, ZG
    Liu, Q
    Liu, JF
    INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (06) : 328 - 330
  • [10] Atmospheric chemistry of cyclohexane:: UV spectra of c-C6H11• and (c-C6H11)O2• radicals, kinetics of the reactions of (c-C6H11)O2• radicals with NO and NO2, and the fate of the alkoxy radical (c-C6H11)O•
    Platz, J
    Sehested, J
    Nielsen, OJ
    Wallington, TJ
    JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (15): : 2688 - 2695
12345