Formation of metal complex in a poly(hydroxamic acid) resin bead

被引:1
|
作者
Taek Seung Lee
Dong Won Jeon
Jai Kyeong Kim
Sung Il Hong
机构
[1] Chungnam National University,Organic & Optoelectronic Materials Lab., Department of Textile Engineering
[2] Ewha Womans University,Department of Clothing and Textiles
[3] Korea Institute of Science and Technology,Electronic Materials and Devices Research Center
[4] Seoul National University,Department of Fiber and Polymer Science
关键词
Chelating resin; Poly(hydroxamic acid); Column extraction; Metal-ligand complex; Energy dispersive spectrum;
D O I
10.1007/BF02875221
中图分类号
学科分类号
摘要
Poly(hydroxamic acid) resin beads were prepared and complexed with various metal ions. We used IR spectroscopy to investigate the structure of metal complex. It proved that the products formed by introduction of metal ions gave stable and colored complex. It was found that the resin bead as synthesized would be a good column packing material for continuous extraction. Energy dispersive spectroscopy was used to study the distribution of metal ions in the resin matrix. It could be tentatively concluded that adsorption and diffusion of metal ions in the chelating resins mainly depended on the loading of the resin matrix which indicated interacting sites with metal ions.
引用
收藏
页码:13 / 17
页数:4
相关论文
共 50 条
  • [1] Poly(hydroxamic acid) chelating resin: the synthesis and uses
    Khodadadi, R.
    Fakhri, S.A.
    Entezami, A.A.
    Iranian Journal of Polymer Science and Technology (English Edition), 1995, 4 (04):
  • [2] Removal of fluoride ion from aqueous solution by a cerium-poly(hydroxamic acid) resin complex
    Haron, MJ
    Yunus, WMZW
    JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2001, 36 (05): : 727 - 734
  • [3] A LEAD(II) ION-SELECTIVE ELECTRODE VIA A METAL-COMPLEX OF POLY(HYDROXAMIC ACID)
    ANUAR, K
    HAMDAN, S
    TALANTA, 1992, 39 (12) : 1653 - 1656
  • [4] EVIDENCE FOR FORMATION OF AN INACTIVE UREASE-HYDROXAMIC ACID COMPLEX
    KOBASHI, K
    HASE, J
    BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1966, 23 (01) : 34 - &
  • [6] SYNTHESIS AND CHARACTERIZATION OF HYDROXAMIC ACID RESIN OF POLY(4-VINYL-2'-CARBOXYBENZOPHENONE)
    KAMBLE, KJ
    PATKAR, DN
    JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 52 (10) : 1361 - 1364
  • [8] Synthesis and characterization of poly(hydroxamic acid) chelating resin from poly(methyl acrylate)-grafted sage starch
    Lutfor, MR
    Sidik, S
    Yunus, WMZW
    Rahman, MZA
    Mansor, A
    Haron, MJ
    JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 79 (07) : 1256 - 1264
  • [9] COMPLEX-FORMATION OF IRON(III) WITH HYDROXAMIC ACID-DERIVATIVES
    SHENDEROVICH, VA
    STRIZHEV, EF
    RYABOI, VI
    ZHURNAL NEORGANICHESKOI KHIMII, 1978, 23 (10): : 2681 - 2687
  • [10] New polymer bearing hydroxamic acid chelating resin for binding of heavy metal ions
    Lutfor, MR
    Silong, S
    Yunus, WMZW
    Rahman, MZA
    Ahmad, M
    Haron, MJ
    JOURNAL OF CHEMICAL RESEARCH-S, 2001, (08): : 326 - 327