An experimental guide to in operando electrochemical Raman spectroscopy

被引：1

作者：

Lenk T. ^{[1
,3
]}

Schröder U. ^{[2
,3
]}

机构：

[1] Institute of Environmental and Sustainable Chemistry, Technische Universität Braunschweig, Braunschweig

[2] Institute of Biochemistry, University of Greifswald, Greifswald

[3] Cluster of Excellence SE2A-Sustainable and Energy-Efficient Aviation, Technische Universität Braunschweig, Braunschweig

来源：

Journal of Solid State Electrochemistry | 2024年 / 28卷 / 3-4期

关键词：

Raman spectroscopy; SERS; Spectroelectrochemistry; Tutorial; Vibrational spectroscopy;

D O I：

10.1007/s10008-023-05381-5

中图分类号：

学科分类号：

摘要：

Electrochemical Raman spectroscopy can provide valuable insights into electrochemical reaction mechanisms. However, it also shows various pitfalls and challenges. This paper gives an overview of the necessary theoretical background, crucial practical considerations for successful measurement, and guidance for in situ/in operando electrochemical Raman spectroscopy. Several parameters must be optimized for suitable reaction and measurement conditions. From the experimental side, considerations for the setup, suitable signal enhancement methods, choice of material, laser, and objective lens are discussed. Different interface phenomena are reviewed in the context of data interpretation and evaluation. © The Author(s) 2023. corrected publication 2023.

引用

页码：965 / 979

页数：14