An X-ray electron study of nanodisperse hydroxyapatite

被引:0
|
作者
I. V. Melikhov
Yu. A. Teterin
V. N. Rudin
A. Yu. Teterin
K. I. Maslakov
A. V. Severin
机构
[1] Moscow State University,Faculty of Chemistry
[2] Kurchatov Institute Russian Research Center,Kurnakov Institute of General and Inorganic Chemistry
[3] Russian Academy of Sciences,undefined
来源
Russian Journal of Physical Chemistry A | 2009年 / 83卷
关键词
Hydroxyapatite; Valence Electron; Sodium Succinate; Electron Binding Energy; Tron Spectrum;
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学科分类号
摘要
Two states of surface valence electrons localized on faces with different molecular reliefs were observed for nanodisperse hydroxyapatite. Thermal treatment of nanocrystals caused a shift ΔEb = 0.5 eV of the spectrum of valence electrons on molecularly rough faces and a shift of 0.8 eV of the spectrum from smooth faces. Similar electron spectrum shifts were observed for sorption, in particular, of sodium succinate. These results are of importance for the diagnostics of various hydroxyapatite kinds, since hydroxyapatite is a constituent mineral component of living organisms, and for the synthesis of medicines with enhanced biological activity used in treatment of various bone diseases.
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页码:91 / 97
页数:6
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