Macro-N-heterocyclic compounds: X-ray photoelectron spectra and structure

被引:0
作者
T. M. Ivanova
M. I. Bazanov
A. V. Petrov
E. S. Yurina
机构
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Ivanovo State University of Chemical Technology,undefined
来源
Russian Journal of Coordination Chemistry | 2006年 / 32卷
关键词
Nitrogen; Spectroscopy; Physical Chemistry; Benzene; Inorganic Chemistry;
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摘要
Bi-, tri-, and tetradentate macroheterocylic ligands, i.e., structural analogs of phthalocyanine, are studied by X-ray photoelectron spectroscopy. The X-ray photoelectron spectra of N1s lines of the nitrogen atoms of these compounds are analyzed. The binding energies and integrated intensities of N1s lines of the nitrogen atoms are determined and the effective charges on the nitrogen atoms are calculated. The structures of bi-, tri-and tetradentate macroheterocyclic ligands containing isoindole, benzene, and pyridine fragments are established on the basis of the data obtained.
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页码:71 / 74
页数:3
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