Functionalised azetidines as ligands: some basic coordination chemistry

被引:0
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作者
Young Hoon Lee
Hyang Hoo Kim
Pierre Thuéry
Jack M. Harrowfield
Woo Taik Lim
Bok Jo Kim
Yang Kim
机构
[1] Kosin University,Department of Chemistry & Advanced Materials
[2] CEA,Institut de Science et d’Ingénierie Supramoléculaires
[3] IRAMIS,Department of Applied Chemistry
[4] SIS2 M,Department of Biomedical Laboratory Science
[5] LCCEf (CNRS URA 331),undefined
[6] Université de Strasbourg,undefined
[7] Andong National University,undefined
[8] Kyungwoon University,undefined
关键词
Azetidines; Metal complexes; Crystal structures; Lattice interactions;
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摘要
Crystal structure determinations on Cu(II) and Zn(II) complexes of tridentate and quadridentate azetidine derivatives show the ligands to be facultative for square-pyramidal and trigonal bipyramidal coordination geometries. While various contributions to the chirality of the complexes are possible, single diastereoisomeric forms (as enantiomer mixtures) have been isolated in all cases in the solid state. Analysis of lattice interactions indicates that H-bonding and aromatic stacking interactions are generally important.
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页码:65 / 71
页数:6
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