Parametric Investigation of the Isothermal Kinetics of Growth of Graphene on a Nickel Catalyst in the Process of Chemical Vapor Deposition of Hydrocarbons

被引：2

作者：

Futko S.I. ^{[1
]}

Shulitskii B.G. ^{[2
]}

Labunov V.A. ^{[2
]}

Ermolaeva E.M. ^{[1
]}

机构：

[1] A. V. Luikov Heat and Mass Transfer Institute, National Academy of Sciences of Belarus, 15 P. Brovka Str., Minsk

[2] Belarusian State University of Information Science and Radio Electronics, 6 P. Brovka Str., Minsk

来源：

Journal of Engineering Physics and Thermophysics | 2016年 / 89卷 / 06期

关键词：

bi-layer graphene; carbon allotropes; chemical vapor deposition; graphene; heterogeneous catalysis; hydrocarbons; isothermal kinetics; nickel catalyst; single-layer graphene; synthesis of graphene; transition metals;

D O I：

10.1007/s10891-016-1518-1

中图分类号：

学科分类号：

摘要：

A kinetic model of isothermal synthesis of multilayer graphene on the surface of a nickel foil in the process of chemical vapor deposition, on it, of hydrocarbons supplied in the pulsed regime is considered. The dependences of the number of graphene layers formed and the time of their growth on the temperature of the process, the concentration of acetylene, and the thickness of the nickel foil were calculated. The regime parameters of the process of chemical vapor deposition, at which single-layer graphene and bi-layer graphene are formed, were determined. The dynamics of growth of graphene domains at chemical-vapor-deposition parameters changing in wide ranges was investigated. It is shown that the time dependences of the rates of growth of single-layer graphene and bi-layer graphene are nonlinear in character and that they are determined by the kinetics of nucleation and growth of graphene and the diffusion flow of carbon atoms in the nickel foil. © 2016, Springer Science+Business Media New York.

引用

页码：1487 / 1499

页数：12

共 16 条

[1]

Novoselov K.S., Nobel lecture: graphene materials in the flatland, Rev. Mod. Phys., 83, pp. 837-849, (2011)

[2]

Kim K.S., Zhao Y., Jang H., Lee S.Y., Kim J.M., Kim K.S., Ahn J.-H., Hong B.H., Large-scale pattern growth of graphene films for stretchable transparent electrodes, Nature, No, 457, 7230, pp. 706-710, (2009)

[3]

Reina A., Jia X.T., Ho J., Nezich D., Son H.B., Bulovic V., Dresselhaus M.S., Kong J., Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition, Nano Lett., 9, pp. 30-35, (2009)

[4]

Zhang Y., Tang T.-T., Girit C., Hao Z., Martin M.C., Zettl A., Crommie M.F., Shen Y.R., Wang F., Direct observation of a widely tunable bandgap in bilayer graphene, Nature, 459, pp. 820-823, (2009)

[5]

Reina A., Thiele S., Jia X.T., Bhaviripudi S., Dresselhaus M.S., Schaefer J.A., Kong J., Growth of large-area single- and bi-layer graphene by controlled carbon precipitation on polycrystalline Ni surfaces, Nano Res, 2, pp. 509-516, (2009)

[6]

Syrkin V.G., Method C.V.D., Chemical Vapor Deposition [in Russian], (2000)

[7]

Li X.S., Cai W.W., An J.H., Kim S., Nah J., Yang D.X., Piner R., Velamakanni A., Jung I., Tutuc E., Banerjee S.K., Colombo L., Ruoff R.S., Large-area synthesis of high-quality and uniform graphene films on copper foils, Science, 324, pp. 1312-1314, (2009)

[8]

Weatherup R.S., Dlubak B., Hofmann S., Kinetic control of catalytic CVD for high-quality graphene at low temperatures, ACS Nano, 6, pp. 9996-10003, (2012)

[9]

Puretzky A.A., Geohegan D.B., Pannala S., Rouleau C.M., Regmi M., Thonnard N., Real-time optical diagnostics of graphene growth induced by pulsed chemical deposition, Nanoscale, 5, pp. 6507-6517, (2013)

[10]

Futko S.I., Shulitskii B.G., Labunov V.A., Ermolaeva E.M., Parametric investigation of the kinetics of growth of carbon-nanotube arrays on iron nanoparticles in the process of chemical vapor deposition of hydrocarbons, J. Eng. Phys. Thermophys., 88, 2, pp. 364-373, (2015)

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