Molecular-mass distribution during radical polymerization of acrylates initiated by pulse laser radiation

被引：0

作者：

A. N. Nikitin

机构：

[1] Russian Academy of Sciences,Institute on Laser and Information Technologies

来源：

Polymer Science Series B | 2009年 / 51卷

关键词：

Laser Radiation; Acrylate; Polymer Science Series; Radical Polymerization; Chain Transfer;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The analytical expressions for the calculation of the molecular-mass distributions for the polymerization of acrylates initiated by the pulse periodic radiation are derived. The intramolecular chain transfer to the polymer is shown to be responsible for the known abnormalities in the molecular-mass distributions during the polymerization of acrylates. A relationship is derived for the characterization of the periodic structure of the molecular-mass distributions and for confirmation of the applicability of the first peak for estimating the avarage rate constant of chain growth.

引用

页码：195 / 203

页数：8

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