Synthesis and structures of the six-coordinate donor-acceptor complexes R3(C6H4O2)Sb...L (R = Ph, L = OSMe2 or ONC5H5; R = Me, L = ONC5H5 or NC5H5) and R3(C2H4O2)Sb...L

被引：29

作者：

Fukin G.K. ^{[1
]}

Zakharov L.N. ^{[1
]}

Domrachev G.A. ^{[1
]}

Fedorov A.Yu. ^{[2
]}

Zaburdyaeva S.N. ^{[2
]}

Dodonov V.A. ^{[2
]}

机构：

[1] G. A. Razuvaev Inst. Organometallic, Russian Academy of Sciences, 49 ul. Tropinina

[2] Department of Chemistry, N. I. Lobachevsky Nizhnii Novgorod, 23a prosp. Gagarina

来源：

Russian Chemical Bulletin | 1999年 / 48卷 / 9期

基金：

俄罗斯基础研究基金会;

关键词：

Molecular and crystal structure; One-pot oxidation reactions; Six-coordinate SbV complexes; Synthesis; X-ray diffraction analysis;

D O I：

10.1007/BF02494820

中图分类号：

学科分类号：

摘要：

One-pot oxidation of R3Sb (R = Ph, Me, Cl, or C6F5) with tert-butyl hydroperoxide in the presence of 1,2-diols and monodentate donor compounds was studied. The structures of the resulting neutral organic donor-acceptor SbV complexes, Ph3(C6H4O2)Sb...OSMe2, Ph3(C6H4O2)Sb...ONC5H5, Me3(C6H4O2,)Sb...ONC5H5, Me3(C6H4O2)Sb...NC5H5, Ph3(C2H4O2)Sb...ONC5H5, and Cl(C6F5),2(C2H4O2)Sb...OPPh3, were established by X-ray diffraction analysis. In these complexes, the coordination environment about the Sb atoms is a distorted octahedron. The Sb-O(N) distances and the Sb-O-E angles (E = S, N, or P) vary over wide ranges.

引用

页码：1722 / 1732

页数：10

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